The country star, a three-time CMA winner, hasn't performed on the awards telecast since 2006.
A release from the CMA says Hill has a new album coming out early next year. It will be her first studio album since 2005's "Fireflies."
Hill joins a star-studded lineup that includes all five entertainer of the year nominees — Taylor Swift, Jason Aldean, Brad Paisley, Blake Shelton and Keith Urban.
Other performers include Lady Antebellum, Miranda Lambert and The Band Perry.
Paisley, the reigning entertainer of the year, will host the awards with Carrie Underwood.
The show airs Nov. 9 on ABC from Nashville.
(Copyright 2011 by Associated Press. All rights reserved. This material may not be published, broadcast, rewritten or redistributed)
Copyright 2011 by Associated Press. All rights reserved.This material may not be published, broadcast, rewritten or redistributed.
Related Content from AccessHollywood.com: